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潍坊中温玻璃鳞片胶泥 中温玻璃鳞片厂家
点击次数:524 发布时间:2018-05-10

在国外,经过实验室的测试,以及二十多年的现场实际应用,证明玻璃鳞片的防腐蚀效果远远超过其他材料,比一般常用的玻璃钢材料,也显得更为优越。近几年来,鳞片树脂涂料之所以能被业界积极的研制和开发,有关人士认为,这主要是由于鳞片树脂,在所组成材料的结构上,具有独特的抗渗透性能。在设备本体与腐蚀介质之间,用一层坚实玻璃鳞片树脂衬里,使之不容易被介质所渗透,来实现所期望的防腐目的。
  经过大量的研究工作,研究者们发现在防腐涂层树脂中混入鳞片填料,不但可以提高其机械强度,降低它的线膨胀系数及固化收缩率,而且还十分容易形成厚浆型的涂料。鳞片填料的加入,还可大大地抑制腐蚀介质的侵入,例如,水和离子类的腐蚀介质,通常它们将通过扩散进入涂层,zui后直至渗透到基体材料。
  因此,掺有玻璃鳞片衬里的重要特征,是可以耐水及其离子的渗透作用。其抑制气体和水蒸汽的渗透性,还取决于玻璃鳞片填料的特性,包括鳞片的尺寸、形状、填充比,鳞片与树脂的粘结力、排列方向,以及涂层的厚度等。 鳞片填料,除玻璃鳞片(GF)外,还有云母片、云母氧化铁( MIO)、石墨、铝片及不锈钢片等。
   目前,国外玻璃鳞片防腐层及其应用技术的发展速度很快,已经从化工、石油、海洋工程等应用领域,拓展到运输业、能源及水处理等各个领域。玻璃鳞片树脂衬里,作为一种新型的防腐蚀厚涂料材料不但作为船身壳体,化学品贮罐,化工厂的塔器、槽和泵,以及油罐车等优良的防腐衬里材料,而且也已成功地应用于钢材或混凝土结构表面的防腐保护层等的用途。
  玻璃鳞片的生产,在我国国内尚处在研制开发的初始阶段,虽然已在某些引进的耐腐设备上获得了成功的应用,但仍未在较大范围内得到推广应用。
  有关人士认为,其主要原因,一是国内广大用户对玻璃鳞片防腐涂层的优越性能的认识,还不十分普遍;二是目前国内玻璃鳞片的产品质量不理想,生产成本比较高。
  经过在显微镜下观察的结果表明,国内生产的玻璃鳞片与日本生产的玻璃鳞片,在结构形式上是相似的,但在分散度方面,不如日本生产的均匀。因而,我国在玻璃鳞片的质量及生产成本方面,均有待于进一步的研究及开发。
二 玻璃鳞片树脂基体
  可以采用各种规格的热固性树脂,例如环氧树脂、聚酯树脂、乙烯基酯树脂、酚醛树脂及呋喃树脂等,作为玻璃鳞片涂层的基体粘结剂。
  如上所述,玻璃鳞片防腐涂层应具有良好的耐腐蚀性及抗渗透性能,因此鳞片树脂材料的选用原则应该主要考虑选用的鳞片树脂基体粘结剂,是否具有抗介质腐蚀和抗渗透的能力,以及它与填料及基层面材的粘结能力等因素。
  选用鳞片树脂基体粘结剂的性能如何,也将直接影响到鳞片树脂防腐涂层的整体性能。
  双酚A型聚酯树脂及乙烯基酯树脂等品种,是目前国内外经常采用的主要鳞片粘结剂品种,因为这些型号的不饱和聚酯树脂,均系属于耐腐蚀型的聚酯树脂,具有良好的耐酸碱性能,并且具有良好的粘结性能等。
  现对常用的鳞片用树脂粘结剂浇铸体的耐化学性能,介绍如下∶乙烯基酯树脂的浇铸体,在25%盐酸(100℃)、10%盐酸(100℃)、5%苛性钠(100℃)、5%氨水(70℃)、甲苯、粗汽油、甲醇、汽油、煤油饱和食盐水(75℃)、水(75℃)等介质中,其耐化学性能均为优良。

 

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